05 December 2020

On Entropy (1940-1949)

"A permanent state is reached, in which no observable events occur. The physicist calls this the state of thermodynamical equilibrium, or of ‘maximum entropy’. Practically, a state of this kind is usually reached very rapidly. Theoretically, it is very often not yet an absolute equilibrium, not yet the true maximum of entropy. But then the final approach to equilibrium is very slow. It could take anything between hours, years, centuries […]." (Erwin Schrödinger, "What is Life?", 1944)

"An isolated system or a system in a uniform environment (which for the present consideration we do best to include as a part of the system we contemplate) increases its entropy and more or less rapidly approaches the inert state of maximum entropy. We now recognize this fundamental law of physics to be just the natural tendency of things to approach the chaotic state (the same tendency that the books of a library or the piles of papers and manuscripts on a writing desk display) unless we obviate it. (The analogue of irregular heat motion, in this case, is our handling those objects now and again without troubling to put them back in their proper places.)" (Erwin Schrödinger, "What is Life?", 1944)

"Every process, event, happening – call it what you will; in a word, everything that is going on in Nature means an increase of the entropy of the part of the world where it is going on. Thus a living organism continually increases its entropy – or, as you may say, produces positive entropy – and thus tends to approach the dangerous state of maximum entropy, which is death. It can only keep aloof from it, i.e. alive, by continually drawing from its environment negative entropy – which is something very positive as we shall immediately see. What an organism feeds upon is negative entropy. Or, to put it less paradoxically, the essential thing in metabolism is that the organism succeeds in freeing itself from all the entropy it cannot help producing while alive." (Erwin Schrödinger, "What is Life?", 1944)

"Hence the awkward expression ‘negative entropy’ can be replaced by a better one: entropy, taken with the negative sign, is itself a measure of order. Thus the device by which an organism maintains itself stationary at a fairly high level of orderliness ( = fairly low level of entropy) really consists in continually sucking orderliness from its environment." (Erwin Schrödinger, "What is Life?", 1944)

"There is no concept in the whole field of physics which is more difficult to understand than is the concept of entropy, nor is there one which is more fundamental." (Francis W Sears, "Mechanics, Heat and Sound", 1944) 

"[A living organism] feeds upon negative entropy […] Thus, the device by which an organism maintains itself stationary at a fairly high level of orderliness really consists in continually sucking orderliness from its environment." (Erwin Schrodinger, "What is Life? The Physical Aspect of the Living Cell", 1944)

"Time itself will come to an end. For entropy points the direction of time. Entropy is the measure of randomness. When all system and order in the universe have vanished, when randomness is at its maximum, and entropy cannot be increased, when there is no longer any sequence of cause and effect, in short when the universe has run down, there will be no direction to time - there will be no time." (Lincoln Barnett, "The Universe and Dr. Einstein", 1948)

"In classical physics, most of the fundamental laws of nature were concerned either with the stability of certain configurations of bodies, e.g. the solar system, or else with the conservation of certain properties of matter, e.g. mass, energy, angular momentum or spin. The outstanding exception was the famous Second Law of Thermodynamics, discovered by Clausius in 1850. This law, as usually stated, refers to an abstract concept called entropy, which for any enclosed or thermally isolated system tends to increase continually with lapse of time. In practice, the most familiar example of this law occurs when two bodies are in contact: in general, heat tends to flow from the hotter body to the cooler. Thus, while the First Law of Thermodynamics, viz. the conservation of energy, is concerned only with time as mere duration, the Second Law involves the idea of trend." (Gerald J Whitrow, "The Structure of the Universe: An Introduction to Cosmology", 1949)

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