On Ludwig Boltzmann

"Let a drop of wine fall into a glass of water; whatever be the law that governs the internal movement of the liquid, we will soon see it tint itself uniformly pink and from th at moment on, however we may agitate the vessel, it appears that the wine and water can separate no more. All this, Maxwell and Boltzmann have explained, but the one who saw it in the cleanest way, in a book that is too little read because it is difficult to read, is Gibbs, in his Principles of Statistical Mechanics." (Henri Poincaré, "La valeur de la science" ["The Value of Science"], 1904)

"It is not surprising, in view of the polydynamic constitution of the genuinely mathematical mind, that many of the major heros of the science, men like Desargues and Pascal, Descartes and Leibnitz, Newton, Gauss and Bolzano, Helmholtz and Clifford, Riemann and Salmon and Plücker and Poincaré, have attained to high distinction in other fields not only of science but of philosophy and letters too. And when we reflect that the very greatest mathematical achievements have been due, not alone to the peering, microscopic, histologic vision of men like Weierstrass, illuminating the hidden recesses, the minute and intimate structure of logical reality, but to the larger vision also of men like Klein who survey the kingdoms of geometry and analysis for the endless variety of things that flourish there, as the eye of Darwin ranged over the flora and fauna of the world, or as a commercial monarch contemplates its industry, or as a statesman beholds an empire; when we reflect not only that the Calculus of Probability is a creation of mathematics but that the master mathematician is constantly required to exercise judgment. - judgment, that is, in matters not admitting of certainty - balancing probabilities not yet reduced nor even reducible perhaps to calculation; when we reflect that he is called upon to exercise a function analogous to that of the comparative anatomist like Cuvier, comparing theories and doctrines of every degree of similarity and dissimilarity of structure; when, finally, we reflect that he seldom deals with a single idea at a tune, but is for the most part engaged in wielding organized hosts of them, as a general wields at once the division of an army or as a great civil administrator directs from his central office diverse and scattered but related groups of interests and operations; then, I say, the current opinion that devotion to mathematics unfits the devotee for practical affairs should be known for false on a priori grounds. And one should be thus prepared to find that as a fact Gaspard Monge, creator of descriptive geometry, author of the classic Applications de l’analyse à la géométrie; Lazare Carnot, author of the celebrated works, Géométrie de position, and Réflections sur la Métaphysique du Calcul infinitesimal; Fourier, immortal creator of the Théorie analytique de la chaleur; Arago, rightful inheritor of Monge’s chair of geometry; Poncelet, creator of pure projective geometry; one should not be surprised, I say, to find that these and other mathematicians in a land sagacious enough to invoke their aid, rendered, alike in peace and in war, eminent public service." (Cassius J Keyser, "Lectures on Science, Philosophy and Art", 1908)

"The difference is that energy is a property of the microstates, and so all observers, whatever macroscopic variables they may choose to define their thermodynamic states, must ascribe the same energy to a system in a given microstate. But they will ascribe different entropies to that microstate, because entropy is not a property of the microstate, but rather of the reference class in which it is embedded. As we learned from Boltzmann, Planck, and Einstein, the entropy of a thermodynamic state is a measure of the number of microstates compatible with the macroscopic quantities that you or I use to define the thermodynamic state." (Edwin T Jaynes, "Papers on Probability, Statistics, and Statistical Physics", 1983)

"It is a remarkable fact that the second law of thermodynamics has played in the history of science a fundamental role far beyond its original scope. Suffice it to mention Boltzmann’s work on kinetic theory, Planck’s discovery of quantum theory or Einstein’s theory of spontaneous emission, which were all based on the second law of thermodynamics." (Ilya Prigogine, 'Time, Structure and Fluctuations", 1993)

"Boltzmann was both a wizard of a mathematician and a physicist of international renown. The magnitude of his output of scientific papers was positively unnerving. He would publish two, three, sometimes four monographs a year; each one was forbiddingly dense, festooned with mathematics, and as much as a hundred pages in length." (George Greenstein, "The Bulldog: A Profile of Ludwig Boltzmann", The American Scholar, 1999)

"Newton was the greatest creative genius physics has ever seen. None of the other candidates for the superlative (Einstein, Maxwell, Boltzmann, Gibbs, and Feynman) has matched Newton’s combined achievements as theoretician, experimentalist, and mathematician. […] If you were to become a time traveler and meet Newton on a trip back to the seventeenth century, you might find him something like the performer who first exasperates everyone in sight and then goes on stage and sings like an angel." William H Cropper,"Great Physicists", 2001)

"Clausius, Maxwell, Boltzmann and Gibbs had a feeling for the statistical interpretation of the second principle of thermodynamics and defended it. But their explanations were based on thought experiments coming from the postulate of the existence of molecules. Only after the discovery of Brownian motion does the interpretation of the second principle of thermodynamics as an absolute law become impossible. Brownian particles rising and falling as a result of the thermal motion of the molecules is a clear demonstration for us of a perpetual motion machine of the second kind. Therefore at the end of the 19th century the investigation of Brownian motion acquired enormous theoretical significance and attracted the attention of many theoretical physicists including Einstein." (Vladimir Zorich, "Mathematical Analysis of Problems in the Natural Sciences", 2010)

"Boltzmann has shown that entropy exists because we describe the world in a blurred fashion. He has demonstrated that entropy is precisely the quantity that counts how many are the different configurations that our blurred vision does not distinguish between. Heat, entropy, and the lower entropy of the past are notions that belong to an approximate, statistical description of nature. The difference between past and future is deeply linked to this blurring." (Carlo Rovelli, "The Order of Time", 2018)

"[...] our vision of the world is blurred because the physical interactions between the part of the world to which we belong and the rest are blind to many variables. This blurring is at the heart of Boltzmann's theory. From this blurring, the concepts of heat and entropy are born - and these are linked to the phenomena that characterize the flow of time. The entropy of a system depends explicitly on blurring. It depends on what I do not register, because it depends on the number of indistinguishable configurations. The same microscopic configuration may be of high entropy with regard to one blurring and low in relation to another." (Carlo Rovelli, "The Order of Time", 2018)