13 February 2020

On Equilibrium (1875-1889)

"Any system in stable chemical equilibrium, subjected to the influence of an external cause tends to change either its temperature or its condensation (pressure, concentration, number of molecules in unit volume), either as a whole or in some of its parts, can only undergo such internal modifications as would, if produced alone, bring about a change of temperature or of condensation of opposite sign to that resulting from the external cause." (Henri L Le Chatelier, "A General Statement of the Laws of Chemical Equilibrium", Comptes rendus Vol. 99, 1884)

"Every situation is an equilibrium of forces; every life is a struggle between opposing forces working within the limits of a certain equilibrium." (Henri-Frédéric Amiel, "Amiel's Journal", 1885)

"Plasticity, then, in the wide sense of the word, means the possession of a structure weak enough to yield to an influence, but strong enough not to yield all at once. Each relatively stable phase of equilibrium in such a structure is marked by what we may call a new set of habits." (William James, "The Laws of Habit", 1887) 

"Every change of one of the factors of an equilibrium occasions a rearrangement of the system in such a direction that the factor in question experiences a change in a sense opposite to the original change." (Henri L Le Chatelier, "Recherches Experimentales et Theoriques sur les Equilibres Chimiques" ["Experimental and Theoretical Research on Chemical Equilibria"], Annales des Mines 8, 1888)

"In every symmetrical system every deformation that tends to destroy the symmetry is complemented by an equal and opposite deformation that tends to restore it. […] One condition, therefore, though not an absolutely sufficient one, that a maximum or minimum of work corresponds to the form of equilibrium, is thus applied by symmetry." (Ernst Mach, "The Science of Mechanics: A Critical and Historical Account of Its Development", 1893)

"That branch of physics which is at once the oldest and the simplest and which is therefore treated as introductory to other departments of this science, is concerned with the motions and equilibrium of masses. It bears the name of mechanics." (Ernst Mach, "The Science of Mechanics: A Critical and Historical Account of Its Development", 1893)

"The whole aspect of the universe changes with this new conception. The idea of force governing the world, of pre-established law, preconceived harmony, disappears to make room for the harmony that [Charles] Fourier had caught a glimpse of: the one which results from the disorderly and incoherent movements of numberless hosts of matter, each of which goes its own way and all of which hold each other in equilibrium." (Peter Kropotkin, "Anarchism: Its Philosophy and Ideal", 1896)

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