Thermodynamics II

"Everywhere […] in the Universe, we discern that closed physical systems evolve in the same sense from ordered states towards a state of complete disorder called thermal equilibrium. This cannot be a consequence of known laws of change, since […] these laws are time symmetric- they permit […] time-reverse. […] The initial conditions play a decisive role in endowing the world with its sense of temporal direction. […] some prescription for initial conditions is crucial if we are to understand […]" (John D Barrow, "Theories of Everything: The Quest for Ultimate Explanation", 1991)

"Three laws governing black hole changes were thus found, but it was soon noticed that something unusual was going on. If one merely replaced the words 'surface area' by 'entropy' and 'gravitational field' by 'temperature', then the laws of black hole changes became merely statements of the laws of thermodynamics. The rule that the horizon surface areas can never decrease in physical processes becomes the second law of thermodynamics that the entropy can never decrease; the constancy of the gravitational field around the horizon is the so-called zeroth law of thermodynamics that the temperature must be the same everywhere in a state of thermal equilibrium. The rule linking allowed changes in the defining quantities of the black hole just becomes the first law of thermodynamics, which is more commonly known as the conservation of energy." (John D Barrow, "Theories of Everything: The Quest for Ultimate Explanation", 1991)

"The second law of thermodynamics, which requires average entropy (or disorder) to increase, does not in any way forbid local order from arising through various mechanisms of self-organization, which can turn accidents into frozen ones producing extensive regularities. Again, such mechanisms are not restricted to complex adaptive systems." (Murray Gell-Mann, "What is Complexity?", Complexity Vol 1 (1), 1995)

"Emergent self-organization in multi-agent systems appears to contradict the second law of thermodynamics. This paradox has been explained in terms of a coupling between the macro level that hosts self-organization (and an apparent reduction in entropy), and the micro level (where random processes greatly increase entropy). Metaphorically, the micro level serves as an entropy 'sink', permitting overall system entropy to increase while sequestering this increase from the interactions where self-organization is desired." (H Van Dyke Parunak & Sven Brueckner, "Entropy and Self-Organization in Multi-Agent Systems", Proceedings of the International Conference on Autonomous Agents, 2001)

"The second law of thermodynamics states that in an isolated system, entropy can only increase, not decrease. Such systems evolve to their state of maximum entropy, or thermodynamic equilibrium. Therefore, physical self-organizing systems cannot be isolated: they require a constant input of matter or energy with low entropy, getting rid of the internally generated entropy through the output of heat ('dissipation'). This allows them to produce ‘dissipative structures’ which maintain far from thermodynamic equilibrium. Life is a clear example of order far from thermodynamic equilibrium." (Carlos Gershenson, "Design and Control of Self-organizing Systems", 2007)

"Thermodynamics is about those properties of systems that are true independent of their mechanism. This is why there is a fundamental asymmetry in the relationship between mechanistic descriptions of systems and thermodynamic descriptions of systems. From the mechanistic information we can deduce all the thermodynamic properties of that system. However, given only thermodynamic information we can deduce nothing about mechanism. This is in spite of the fact that thermodynamics makes it possible for us to reject classes of models such as perpetual motion machines." (Carlos Gershenson, “Design and Control of Self-organizing Systems”, 2007)

"Second Law of thermodynamics is not an equality, but an inequality, asserting merely that a certain quantity referred to as the entropy of an isolated system - which is a measure of the system’s disorder, or ‘randomness’ - is greater (or at least not smaller) at later times than it was at earlier times." (Roger Penrose, "Cycles of Time: An Extraordinary New View of the Universe", 2010)

"The laws of thermodynamics tell us something quite different. Economic activity is merely borrowing low-entropy energy inputs from the environment and transforming them into temporary products and services of value. In the transformation process, often more energy is expended and lost to the environment than is embedded in the particular good or service being produced." (Jeremy Rifkin, "The Third Industrial Revolution", 2011)

"The reactions that break down large molecules into small ones do not require an input of energy, but the reactions that build up large molecules require and input of energy. This is consistent with the laws of thermodynamics, which say that large, orderly molecules tend to break down into small, disorderly molecules." (Stanley A Rice, "Life of Earth: Portrait of a Beautiful, Middle-aged Stressed-out World", 2011)

"The Second Law of Thermodynamics states that in an isolated system (one that is not taking in energy), entropy never decreases. (The First Law is that energy is conserved; the Third, that a temperature of absolute zero is unreachable.) Closed systems inexorably become less structured, less organized, less able to accomplish interesting and useful outcomes, until they slide into an equilibrium of gray, tepid, homogeneous monotony and stay there." (Steven Pinker, "The Second Law of Thermodynamics", 2017)