21 November 2025

On Thermodynamics (1975-1999)

"A mathematical model is any complete and consistent set of mathematical equations which are designed to correspond to some other entity, its prototype. The prototype may be a physical, biological, social, psychological or conceptual entity, perhaps even another mathematical model. " (Rutherford Aris, "Mathematical Modelling", 1978)"

"It is a remarkable empirical fact that mathematics can be based on set theory. More precisely, all mathematical objects can be coded as sets" (in the cumulative hierarchy built by transfinitely iterating the power set operation, starting with the empty set). And all their crucial properties can be proved from the axioms of set theory." (. . . ) At first sight, category theory seems to be an exception to this general phenomenon. It deals with objects, like the categories of sets, of groups etc. that are as big as the whole universe of sets and that therefore do not admit any evident coding as sets. Furthermore, category theory involves constructions, like the functor category, that lead from these large categories to even larger ones. Thus, category theory is not just another field whose set-theoretic foundation can be left as an exercise. An interaction between category theory and set theory arises because there is a real question: What is the appropriate set-theoretic foundation for category theory?" (Andreas Blass, "The interaction between category theory and set theory", 1983) 

"The difference is that energy is a property of the microstates, and so all observers, whatever macroscopic variables they may choose to define their thermodynamic states, must ascribe the same energy to a system in a given microstate. But they will ascribe different entropies to that microstate, because entropy is not a property of the microstate, but rather of the reference class in which it is embedded. As we learned from Boltzmann, Planck, and Einstein, the entropy of a thermodynamic state is a measure of the number of microstates compatible with the macroscopic quantities that you or I use to define the thermodynamic state." (Edwin T Jaynes, "Papers on Probability, Statistics, and Statistical Physics", 1983)

"There is no end to this search for the ultimate ‘true’ entropy until we have reached the point where we control the location of each atom independently. But just at that point the notion of entropy collapses, and we are no longer talking thermodynamics." (Edwin T Jaynes, "Papers on Probability, Statistics, and Statistical Physics", 1983)

"The increase of disorder or entropy with time is one example of what is called an arrow of time something that gives a direction to time and distinguishes the past from the future. There are at least three different directions of time. First, there is the thermodynamic arrow of time - the direction of time in which disorder or entropy increases. Second, there is the psychological arrow of time. This is the direction in which we feel time passes - the direction of time in which we remember the past, but not the future. Third, there is the cosmological arrow of time. This is the direction of time in which the universe is expanding rather than contracting." (Stephen W. Hawking, "The Direction of Time", New Scientist 46, 1987)

"Just like a computer, we must remember things in the order in which entropy increases. This makes the second law of thermodynamics almost trivial. Disorder increases with time because we measure time in the direction in which disorder increases. " (Stephen Hawking, "A Brief History of Time", 1988)

"The concept of entropy relates to the tendency of things to move toward greater disorder, or disorganization. […] The second law of thermodynamics expresses precisely the same concept. This states that heat dissipates from a central source and the energy becomes degraded, although total energy remains constant" (the first law of thermodynamics). Entropy suggests that organisms, organizations, societies, machines, and so on, will rapidly deteriorate into disorder and death." The reason they do not is because animate things can self-organize and inanimate things may be serviced by man. These are negentropic activities which require energy. Energy, however, can be made available only by further degradation. Ultimately, therefore, entropy wins the day and the attempts to create order can seem rather a daunting task in the entropic scheme of things. Holding back entropy, however, is another of the challenging tasks for the systems scientist." (Robert L Flood & Ewart R Carson, "Dealing with Complexity: An introduction to the theory and application of systems", 1988)

"Life is nature's solution to the problem of preserving information despite the second law of thermodynamics." (Howard L Resnikoff, "The Illusion of Reality", 1989)

"Quantum mechanics, like other physical theories, consists of a mathematical part, and an operational part that tells you how a certain piece of physical reality is described by the mathematics. Both the mathematical and the operational aspects of quantum mechanics are straightforward and involve no logical paradoxes. Furthermore, the agreement between theory and experiment is as good as one can hope for. Nevertheless, the new mechanics has given rise to many controversies, which involve its probabilistic aspect, the relation of its operational concepts with those of classical mechanics […]" (David Ruelle, "Chance and Chaos", 1991)

"Three laws governing black hole changes were thus found, but it was soon noticed that something unusual was going on. If one merely replaced the words 'surface area' by 'entropy' and 'gravitational field' by 'temperature', then the laws of black hole changes became merely statements of the laws of thermodynamics. The rule that the horizon surface areas can never decrease in physical processes becomes the second law of thermodynamics that the entropy can never decrease; the constancy of the gravitational field around the horizon is the so-called zeroth law of thermodynamics that the temperature must be the same everywhere in a state of thermal equilibrium. The rule linking allowed changes in the defining quantities of the black hole just becomes the first law of thermodynamics, which is more commonly known as the conservation of energy." (John D Barrow, "Theories of Everything: The Quest for Ultimate Explanation", 1991)

"The new information technologies can be seen to drive societies toward increasingly dynamic high-energy regions further and further from thermodynamical equilibrium, characterized by decreasing specific entropy and increasingly dense free-energy flows, accessed and processed by more and more complex social, economic, and political structures." (Ervin László, "Information Technology and Social Change: An Evolutionary Systems Analysis", Behavioral Science 37, 1992)

"General evolution theory, based on the integration of the relevant tenets of general system theory, cybernetics, information and communication theory, chaos theory, dynamical systems theory, and nonequilibrium thermodynamics, can convey a sound understanding of the laws and dynamics that govern the evolution of complex systems in the various realms of investigation. […] The basic notions of this new discipline can be developed to give an adequate account of the dynamical evolution of human societies as well. Such an account could furnish the basis of a system of knowledge better able to orient human beings and societies in their rapidly changing milieu." (Ervin Laszlo et al.,"Evolution: The grand synthesis", 1993)

"The description of the evolutionary trajectory of dynamical systems as irreversible, periodically chaotic, and strongly nonlinear fits certain features of the historical development of human societies. But the description of evolutionary processes, whether in nature or in history, has additional elements. These elements include such factors as the convergence of existing systems on progressively higher organizational levels, the increasingly efficient exploitation by systems of the sources of free energy in their environment, and the complexification of systems structure in states progressively further removed from thermodynamic equilibrium." (Ervin László et al, "The Evolution of Cognitive Maps: New Paradigms for the Twenty-first Century", 1993)

"The second law of thermodynamics, which requires average entropy" (or disorder) to increase, does not in any way forbid local order from arising through various mechanisms of self-organization, which can turn accidents into frozen ones producing extensive regularities. Again, such mechanisms are not restricted to complex adaptive systems." (Murray Gell-Mann, "What is Complexity?", Complexity Vol 1" (1), 1995)

"Contrary to what happens at equilibrium, or near equilibrium, systems far from equilibrium do not conform to any minimum principle that is valid for functions of free energy or entropy production." (Ilya Prigogine, "The End of Certainty: Time, Chaos, and the New Laws of Nature", 1996)

"No one has yet succeeded in deriving the second law from any other law of nature. It stands on its own feet. It is the only law in our everyday world that gives a direction to time, which tells us that the universe is moving toward equilibrium and which gives us a criteria for that state, namely, the point of maximum entropy, of maximum probability. The second law involves no new forces. On the contrary, it says nothing about forces whatsoever." (Brian L Silver, "The Ascent of Science", 1998)

"There is no over-arching theory of complexity that allows us to ignore the contingent aspects of complex systems. If something really is complex, it cannot by adequately described by means of a simple theory. Engaging with complexity entails engaging with specific complex systems. Despite this we can, at a very basic level, make general remarks concerning the conditions for complex behaviour and the dynamics of complex systems. Furthermore, I suggest that complex systems can be modelled." (Paul Cilliers," Complexity and Postmodernism", 1998)

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