On Thermodynamics (1925-1949)

"It is not surprising that our language should be incapable of describing the processes occurring within the atoms, for, as has been remarked, it was invented to describe the experiences of daily life, and these consist only of processes involving exceedingly large numbers of atoms. Furthermore, it is very difficult to modify our language so that it will be able to describe these atomic processes, for words can only describe things of which we can form mental pictures, and this ability, too, is a result of daily experience. Fortunately, mathematics is not subject to this limitation, and it has been possible to invent a mathematical scheme - the quantum theory - which seems entirely adequate for the treatment of atomic processes; for visualisation, however, we must content ourselves with two incomplete analogies - the wave picture and the corpuscular picture." (Werner Heisenberg, "On Quantum Physics", 1930)

"It was not easy for a person brought up in the ways of classical thermodynamics to come around to the idea that gain of entropy eventually is nothing more nor less than loss of information." (Gilbert N Lewis, [Letter to Irving Langmuir] 1930)

"True equilibria can occur only in closed systems and that, in open systems, disequilibria called ‘steady states’, or ‘flow equilibria’ are the predominant and characteristic feature. According to the second law of thermodynamics a closed system must eventually attain a time-independent equilibrium state, with maximum entropy and minimum free energy. An open system may, under certain conditions, attain a time-independent state where the system remains constant as a whole and in its phases, though there is a continuous flow of component materials. This is called a steady state. Steady states are irreversible as a whole. […] A closed system in equilibrium does not need energy for its preservation, nor can energy be obtained from it. In order to perform work, a system must be in disequilibrium, tending toward equilibrium and maintaining a steady state, Therefore the character of an open system is the necessary condition for the continuous working capacity of the organism." (Ludwig on Bertalanffy, "Theoretische Biologie: Band 1: Allgemeine Theorie, Physikochemie, Aufbau und Entwicklung des Organismus", 1932)

"When a transfer of matter to or from a system is also possible, the system may be called an open system." (Frank H MacDougall, "Thermodynamics and chemistry", ?1939)

"A permanent state is reached, in which no observable events occur. The physicist calls this the state of thermodynamical equilibrium, or of ‘maximum entropy’. Practically, a state of this kind is usually reached very rapidly. Theoretically, it is very often not yet an absolute equilibrium, not yet the true maximum of entropy. But then the final approach to equilibrium is very slow. It could take anything between hours, years, centuries […]." (Erwin Schrödinger, "What is Life?", 1944)

"An isolated system or a system in a uniform environment (which for the present consideration we do best to include as a part of the system we contemplate) increases its entropy and more or less rapidly approaches the inert state of maximum entropy. We now recognize this fundamental law of physics to be just the natural tendency of things to approach the chaotic state (the same tendency that the books of a library or the piles of papers and manuscripts on a writing desk display) unless we obviate it. (The analogue of irregular heat motion, in this case, is our handling those objects now and again without troubling to put them back in their proper places.)" (Erwin Schrödinger, "What is Life?", 1944)

"Every process, event, happening – call it what you will; in a word, everything that is going on in Nature means an increase of the entropy of the part of the world where it is going on. Thus a living organism continually increases its entropy – or, as you may say, produces positive entropy – and thus tends to approach the dangerous state of maximum entropy, which is death. It can only keep aloof from it, i.e. alive, by continually drawing from its environment negative entropy – which is something very positive as we shall immediately see. What an organism feeds upon is negative entropy. Or, to put it less paradoxically, the essential thing in metabolism is that the organism succeeds in freeing itself from all the entropy it cannot help producing while alive." (Erwin Schrödinger, "What is Life?", 1944

"How would we express in terms of the statistical theory the marvelous faculty of a living organism, by which it delays the decay into thermodynamical equilibrium" (death)? [...] the device by which an organism maintains itself stationary at a fairly high level of orderliness […] really consists in continually sucking orderliness from its environment." (Erwin Schrödinger, "What Is Life?", 1944)

"A theory is the more impressive the greater the simplicity of its premises is, the more different kinds of things it relates, and the more extended is its area of applicability. Therefore the deep impression which classical thermodynamics made upon me. It is the only physical theory of universal content concerning which I am convinced that, within the framework of the applicability of its basic concepts, it will never be overthrown" (for the special attention of those who are skeptics on principle)." (Albert Einstein, "Autobiographical Notes", 1949)

"In classical physics, most of the fundamental laws of nature were concerned either with the stability of certain configurations of bodies, e.g. the solar system, or else with the conservation of certain properties of matter, e.g. mass, energy, angular momentum or spin. The outstanding exception was the famous Second Law of Thermodynamics, discovered by Clausius in 1850. This law, as usually stated, refers to an abstract concept called entropy, which for any enclosed or thermally isolated system tends to increase continually with lapse of time. In practice, the most familiar example of this law occurs when two bodies are in contact: in general, heat tends to flow from the hotter body to the cooler. Thus, while the First Law of Thermodynamics, viz. the conservation of energy, is concerned only with time as mere duration, the Second Law involves the idea of trend." (Gerald J Whitrow, "The Structure of the Universe: An Introduction to Cosmology", 1949)