Peter G Tait - Collected Quotes

"There seems to me to be something analogous to polarized intensity in the pure imaginary part; and to unpolarized energy (indifferent to direction) in the real part of a quaternion: and thus we have some slight glimpse of a future Calculus of Polarities. This is certainly very vague […]" (Sir William R Hamilton, "On Quaternions; or on a new System of Imaginaries in Algebra", 1844) 

"The next grand extensions of mathematical physics will, in all likelihood, be furnished by quaternions." (Peter G Tait, "Note on a Quaternion Transformation", [communication read] 1863) 

"Nothing can be more fatal to progress than a too confident reliance on mathematical symbols; for the student is only too apt to take the easier course, and consider the formula not the fact as the physical reality." (William T Kelvin & Peter G Tait, "Treatise on Natural Philosophy", 1867)

"From the earliest times man's apprehension of the causes and connections of natural phenomena has been rendered uncertain and imperfect by his wilfully ignoring the great fact that Natural Philosophy is an experimental, and not an intuitive, science." (Peter G Tait, "Sketch Of Thermodynamics", 1868)

"It is very desirable to have a word to express the Availability for work of the heat in a given magazine; a term for that possession, the waste of which is called Dissipation. Unfortunately the excellent word Entropy, which Clausius has introduced in this connexion, is applied by him to the negative of the idea we most naturally wish to express. It would only confuse the student if we were to endeavour to invent another term for our purpose. But the necessity for some such term will be obvious from the beautiful examples which follow. And we take the liberty of using the term Entropy in this altered sense [...] The entropy of the universe tends continually to zero." (Peter G Tait, "Sketch Of Thermodynamics", 1868)

"There is nothing physical to be learned a priori. We have no right whatever to ascertain a single physical truth without seeking for it physically, unless it be a necessary consequence of other truths already acquired by experiment, in which case mathematical reasoning is alone requisite." (Peter G Tait, "Lectures on Some Recent Advances in Physical Science, With a Special, Lecture on Force", 1876)

"There is a necessity for perfect definiteness of language in all truly Scientific work." (Peter G Tait, "On the Formula of Evolution", Nature, November 23, 1880)

"An exact or adequate conception of matter itself, could we obtain it, would almost certainly be something extremely unlike any conception of it which our senses and our reason will ever enable us to form. [...] The discovery of the ultimate nature of matter is probably beyond the range of human intelligence." (Peter G Tait, "Properties of Matter", 1890)

"To [the scientific man] the discovery of a new law of nature, or even of a new experimental fact, or the invention of a novel mathematical method, no matter who has been the first to reach it, is an event of an order altogether different from, and higher than, those which are so profusely chronicled in the newspapers." (Peter G Tait)

Thermodynamics IV

"It is impossible by means of inanimate material agency, to derive mechanical effect from any portion of matter by cooling it below the temperature of the coldest of the surrounding objects. [Footnote: ] If this axiom be denied for all temperatures, it would have to be admitted that a self-acting machine might be set to work and produce mechanical effect by cooling the sea or earth, with no limit but the total loss of heat from the earth and sea, or in reality, from the whole material world." (William Thomson, "On the Dynamical Theory of Heat with Numerical Results Deduced from Mr Joule's Equivalent of a Thermal Unit and M. Regnault's Observations on Steam", Transactions of the Royal Society of Edinburgh, 1851)

"Though the ultimate state of the universe may be its vital and psychical extinction, there is nothing in physics to interfere with the hypothesis that the penultimate state might be the millennium - in other words a state in which a minimum of difference of energy - level might have its exchanges so skillfully canalises that a maximum of happy and virtuous consciousness would be the only result." (William James, [Letter to Henry Adams] 1910)" (William James, [Letter to Henry Adams] 1910)

"Organic evolution has its physical analogue in the universal law that the world tends, in all its parts and particles, to pass from certain less probable to certain more probable configurations or states. This is the second law of thermodynamics." (D'Arcy Wentworth Thompson, "On Growth and Form", 1917)

"In classical physics, most of the fundamental laws of nature were concerned either with the stability of certain configurations of bodies, e.g. the solar system, or else with the conservation of certain properties of matter, e.g. mass, energy, angular momentum or spin. The outstanding exception was the famous Second Law of Thermodynamics, discovered by Clausius in 1850. This law, as usually stated, refers to an abstract concept called entropy, which for any enclosed or thermally isolated system tends to increase continually with lapse of time. In practice, the most familiar example of this law occurs when two bodies are in contact: in general, heat tends to flow from the hotter body to the cooler. Thus, while the First Law of Thermodynamics, viz. the conservation of energy, is concerned only with time as mere duration, the Second Law involves the idea of trend." (Gerald J Whitrow, "The Structure of the Universe: An Introduction to Cosmology", 1949)

"The second law of thermodynamics provides a more modem (and a more discouraging) example of the maximum principle: the entropy (disorder) of the universe tends toward a maximum." (James R Newman, "The World of Mathematics" Vol. II, 1956)

"[...] thermodynamics knows of no such notion as the 'entropy of a physical system'. Thermodynamics does have the concept of the entropy of a thermodynamic system; but a given physical system corresponds to many different thermodynamic systems." (Edwin T Jaynes, "Gibbs vs Boltzmann Entropies", 1964)

"'You cannot base a general mathematical theory on imprecisely defined concepts. You can make some progress that way; but sooner or later the theory is bound to dissolve in ambiguities which prevent you from extending it further.' Failure to recognize this fact has another unfortunate consequence which is, in a practical sense, even more disastrous: 'Unless the conceptual problems of a field have been clearly resolved, you cannot say which mathematical problems are the relevant ones worth working on; and your efforts are more than likely to be wasted.'" (Edwin T Jaynes, "Foundations of Probability Theory and Statistical Mechanics", 1967)

"There is no end to this search for the ultimate ‘true’ entropy until we have reached the point where we control the location of each atom independently. But just at that point the notion of entropy collapses, and we are no longer talking thermodynamics." (Edwin T Jaynes, "Papers on Probability, Statistics, and Statistical Physics", 1983)

"No one has yet succeeded in deriving the second law from any other law of nature. It stands on its own feet. It is the only law in our everyday world that gives a direction to time, which tells us that the universe is moving toward equilibrium and which gives us a criteria for that state, namely, the point of maximum entropy, of maximum probability. The second law involves no new forces. On the contrary, it says nothing about forces whatsoever." (Brian L Silver, "The Ascent of Science", 1998)

On Physics (1900-1909)

"The laws of thermodynamics, as empirically determined, express the approximate and probable behavior of systems of a great number of particles, or, more precisely, they express the laws of mechanics for such systems as they appear to beings who have not the fineness of perception to enable them to appreciate quantities of the order of magnitude of those which relate to single particles, and who cannot repeat their experiments often enough to obtain any but the most probable results." (Josiah W Gibbs, "Elementary Principles in Statistical Mechanics", 1902)

"Chemistry and physics are experimental sciences; and those who are engaged in attempting to enlarge the boundaries of science by experiment are generally unwilling to publish speculations; for they have learned, by long experience, that it is unsafe to anticipate events. It is true, they must make certain theories and hypotheses. They must form some kind of mental picture of the relations between the phenomena which they are trying to investigate, else their experiments would be made at random, and without connection." (William Ramsay, "Radium and Its Products", Harper’s Magazine, 1904)

"The mathematical formula is the point through which all the light gained by science passes in order to be of use to practice; it is also the point in which all knowledge gained by practice, experiment, and observation must be concentrated before it can be scientifically grasped. The more distant and marked the point, the more concentrated will be the light coming from it, the more unmistakable the insight conveyed. All scientific thought, from the simple gravitation formula of Newton, through the more complicated formulae of physics and chemistry, the vaguer so called laws of organic and animated nature, down to the uncertain statements of psychology and the data of our social and historical knowledge, alike partakes of this characteristic, that it is an attempt to gather up the scattered rays of light, the different parts of knowledge, in a focus, from whence it can be again spread out and analyzed, according to the abstract processes of the thinking mind. But only when this can be done with a mathematical precision and accuracy is the image sharp and well-defined, and the deductions clear and unmistakable. As we descend from the mechanical, through the physical, chemical, and biological, to the mental, moral, and social sciences, the process of focalization becomes less and less perfect, - the sharp point, the focus, is replaced by a larger or smaller circle, the contours of the image become less and less distinct, and with the possible light which we gain there is mingled much darkness, the sources of many mistakes and errors. But the tendency of all scientific thought is toward clearer and clearer definition; it lies in the direction of a more and more extended use of mathematical measurements, of mathematical formulae." (John T Merz, "History of European Thought in the 19th Century" Vol. 1, 1904)

"The science of physics does not only give us [mathematicians] an opportunity to solve problems, but helps us also to discover the means of solving them, and it does this in two ways: it leads us to anticipate the solution and suggests suitable lines of argument." (Henri Poincaré, "La valeur de la science" ["The Value of Science"], 1905)

"[...] as for physics, it has developed remarkably as a precision science, in such a way that we can justifiably claim that the majority of all the greatest discoveries in physics are very largely based on the high degree of accuracy which can now be obtained in measurements made during the study of physical phenomena. [... Accuracy of measurement] is the very root, the essential condition, of our penetration deeper into the laws of physics - our only way to new discoveries." (K Bernhard Hasselberg, [Nobel Lecture] 1907)

"If the aim of physical theories is to explain experimental laws, theoretical physics is not an autonomous science; it is subordinate to metaphysics." (Pierre-Maurice-Marie Duhem, "The Aim and Structure of Physical Theory", 1908)

"It is impossible to follow the march of one of the greatest theories of physics, to see it unroll majestically its regular deductions starting from initial hypotheses, to see its consequences represent a multitude of experimental laws down to the smallest detail, without being charmed by the beauty of such a construction, without feeling keenly that such a creation of the human mind is truly a work of art." (Pierre-Maurice-Marie DuhemDuhem, "The Aim and Structure of Physical Theory", 1908)

"[...] physics makes progress because experiment constantly causes new disagreements to break out between laws and facts, and because physicists constantly touch up and modify laws in order that they may more faithfully represent the facts." (Pierre-Maurice-Marie Duhem, "The Aim and Structure of Physical Theory", 1908)

"The laws of physics are therefore provisional in that the symbols they relate too simple to represent reality completely." (Pierre-Maurice-Marie Duhem, "The Aim and Structure of Physical Theory", 1908)

Thermodynamics I

"The second fundamental theorem [the second law of thermodynamics], in the form which I have given to it, asserts that all transformations occurring in nature may take place in a certain direction, which I have assumed as positive, by themselves, that is, without compensation […] the entire condition of the universe must always continue to change in that first direction, and the universe must consequently approach incessantly a limiting condition. […] For every body two magnitudes have thereby presented themselves - the transformation value of its thermal content [the amount of inputted energy that is converted to 'work'], and its disgregation [separation or disintegration]; the sum of which constitutes its entropy." (Rudolf Clausius, "The Mechanical Theory of Heat", 1867)

"Since a given system can never of its own accord go over into another equally probable state but into a more probable one, it is likewise impossible to construct a system of bodies that after traversing various states returns periodically to its original state, that is a perpetual motion machine." (Ludwig E Boltzmann, "The Second Law of Thermodynamics", [Address to a Formal meeting of the Imperial Academy of Science], 1886)

"The second law of thermodynamics appears solely as a law of probability, entropy as a measure of the probability, and the increase of entropy is equivalent to a statement that more probable events follow less probable ones." (Max Planck, "A Survey of Physics", 1923)

"It was not easy for a person brought up in the ways of classical thermodynamics to come around to the idea that gain of entropy eventually is nothing more nor less than loss of information." (Gilbert N Lewis, [Letter to Irving Langmuir] 1930)

"True equilibria can occur only in closed systems and that, in open systems, disequilibria called ‘steady states’, or ‘flow equilibria’ are the predominant and characteristic feature. According to the second law of thermodynamics a closed system must eventually attain a time-independent equilibrium state, with maximum entropy and minimum free energy. An open system may, under certain conditions, attain a time-independent state where the system remains constant as a whole and in its phases, though there is a continuous flow of component materials. This is called a steady state. Steady states are irreversible as a whole. […] A closed system in equilibrium does not need energy for its preservation, nor can energy be obtained from it. In order to perform work, a system must be in disequilibrium, tending toward equilibrium and maintaining a steady state, Therefore the character of an open system is the necessary condition for the continuous working capacity of the organism." (Ludwig on Bertalanffy, "Theoretische Biologie: Band 1: Allgemeine Theorie, Physikochemie, Aufbau und Entwicklung des Organismus", 1932)

"When a transfer of matter to or from a system is also possible, the system may be called an open system." (Frank H MacDougall, "Thermodynamics and chemistry", ?1939)

"A theory is the more impressive the greater the simplicity of its premises is, the more different kinds of things it relates, and the more extended is its area of applicability. Therefore the deep impression which classical thermodynamics made upon me. It is the only physical theory of universal content concerning which I am convinced that, within the framework of the applicability of its basic concepts, it will never be overthrown (for the special attention of those who are skeptics on principle)." (Albert Einstein, "Autobiographical Notes", 1949)

"Reversible processes are not, in fact, processes at all, they are sequences of states of equilibrium. The processes which we encounter in real life are always irreversible processes." (Arnold Sommerfeld, "Thermodynamics and Statistical Mechanics", Lectures on Theoretical - Physics Vol. V, 1956)

Thermodynamics III

"My analysis of living systems uses concepts of thermodynamics, information theory, cybernetics, and systems engineering, as well as the classical concepts appropriate to each level. The purpose is to produce a description of living structure and process in terms of input and output, flows through systems, steady states, and feedbacks, which will clarify and unify the facts of life." (James G Miller, "Living Systems: Basic Concepts", 1969)

"In an isolated system, which cannot exchange energy and matter with the surroundings, this tendency is expressed in terms of a function of the macroscopic state of the system: the entropy." (Ilya Prigogine, "Thermodynamics of Evolution", 1972)

"[The] system may evolve through a whole succession of transitions leading to a hierarchy of more and more complex and organized states. Such transitions can arise in nonlinear systems that are maintained far from equilibrium: that is, beyond a certain critical threshold the steady-state regime become unstable and the system evolves into a new configuration." (Ilya Prigogine, Gregoire Micolis & Agnes Babloyantz, "Thermodynamics of Evolution", Physics Today 25 (11), 1972)

"The evolution of a physicochemical system leads to an equilibrium state of maximum disorder." (Ilya Prigogine, "Thermodynamics of Evolution", 1972)

"The functional order maintained within living systems seems to defy the Second Law; nonequilibrium thermodynamics describes how such systems come to terms with entropy." (Ilya Prigogine, "Thermodynamics of Evolution", 1972)

"When matter is becoming disturbed by non-equilibrium conditions it organizes itself, it wakes up. It happens that our world is a non-equilibrium system." (Ilya Prigogine, "Thermodynamics of Evolution", 1972)

"There is nothing supernatural about the process of self-organization to states of higher entropy; it is a general property of systems, regardless of their materials and origin. It does not violate the Second Law of thermodynamics since the decrease in entropy within an open system is always offset by the increase of entropy in its surroundings." (Ervin László, "Introduction to Systems Philosophy", 1972)

"Concepts form the basis for any science. These are ideas, usually somewhat vague (especially when first encountered), which often defy really adequate definition. The meaning of a new concept can seldom be grasped from reading a one-paragraph discussion. There must be time to become accustomed to the concept, to investigate it with prior knowledge, and to associate it with personal experience. Inability to work with details of a new subject can often be traced to inadequate understanding of its basic concepts." (William C Reynolds & Harry C Perkins, "Engineering Thermodynamics", 1977)

"Just like a computer, we must remember things in the order in which entropy increases. This makes the second law of thermodynamics almost trivial. Disorder increases with time because we measure time in the direction in which disorder increases."  (Stephen Hawking, "A Brief History of Time", 1988)

"Life is nature's solution to the problem of preserving information despite the second law of thermodynamics." (Howard L Resnikoff, "The Illusion of Reality", 1989)

Thermodynamics II

"Everywhere […] in the Universe, we discern that closed physical systems evolve in the same sense from ordered states towards a state of complete disorder called thermal equilibrium. This cannot be a consequence of known laws of change, since […] these laws are time symmetric- they permit […] time-reverse. […] The initial conditions play a decisive role in endowing the world with its sense of temporal direction. […] some prescription for initial conditions is crucial if we are to understand […]" (John D Barrow, "Theories of Everything: The Quest for Ultimate Explanation", 1991)

"Three laws governing black hole changes were thus found, but it was soon noticed that something unusual was going on. If one merely replaced the words 'surface area' by 'entropy' and 'gravitational field' by 'temperature', then the laws of black hole changes became merely statements of the laws of thermodynamics. The rule that the horizon surface areas can never decrease in physical processes becomes the second law of thermodynamics that the entropy can never decrease; the constancy of the gravitational field around the horizon is the so-called zeroth law of thermodynamics that the temperature must be the same everywhere in a state of thermal equilibrium. The rule linking allowed changes in the defining quantities of the black hole just becomes the first law of thermodynamics, which is more commonly known as the conservation of energy." (John D Barrow, "Theories of Everything: The Quest for Ultimate Explanation", 1991)

"The second law of thermodynamics, which requires average entropy (or disorder) to increase, does not in any way forbid local order from arising through various mechanisms of self-organization, which can turn accidents into frozen ones producing extensive regularities. Again, such mechanisms are not restricted to complex adaptive systems." (Murray Gell-Mann, "What is Complexity?", Complexity Vol 1 (1), 1995)

"Emergent self-organization in multi-agent systems appears to contradict the second law of thermodynamics. This paradox has been explained in terms of a coupling between the macro level that hosts self-organization (and an apparent reduction in entropy), and the micro level (where random processes greatly increase entropy). Metaphorically, the micro level serves as an entropy 'sink', permitting overall system entropy to increase while sequestering this increase from the interactions where self-organization is desired." (H Van Dyke Parunak & Sven Brueckner, "Entropy and Self-Organization in Multi-Agent Systems", Proceedings of the International Conference on Autonomous Agents, 2001)

"The second law of thermodynamics states that in an isolated system, entropy can only increase, not decrease. Such systems evolve to their state of maximum entropy, or thermodynamic equilibrium. Therefore, physical self-organizing systems cannot be isolated: they require a constant input of matter or energy with low entropy, getting rid of the internally generated entropy through the output of heat ('dissipation'). This allows them to produce ‘dissipative structures’ which maintain far from thermodynamic equilibrium. Life is a clear example of order far from thermodynamic equilibrium." (Carlos Gershenson, "Design and Control of Self-organizing Systems", 2007)

"Thermodynamics is about those properties of systems that are true independent of their mechanism. This is why there is a fundamental asymmetry in the relationship between mechanistic descriptions of systems and thermodynamic descriptions of systems. From the mechanistic information we can deduce all the thermodynamic properties of that system. However, given only thermodynamic information we can deduce nothing about mechanism. This is in spite of the fact that thermodynamics makes it possible for us to reject classes of models such as perpetual motion machines." (Carlos Gershenson, “Design and Control of Self-organizing Systems”, 2007)

"Second Law of thermodynamics is not an equality, but an inequality, asserting merely that a certain quantity referred to as the entropy of an isolated system - which is a measure of the system’s disorder, or ‘randomness’ - is greater (or at least not smaller) at later times than it was at earlier times." (Roger Penrose, "Cycles of Time: An Extraordinary New View of the Universe", 2010)

"The laws of thermodynamics tell us something quite different. Economic activity is merely borrowing low-entropy energy inputs from the environment and transforming them into temporary products and services of value. In the transformation process, often more energy is expended and lost to the environment than is embedded in the particular good or service being produced." (Jeremy Rifkin, "The Third Industrial Revolution", 2011)

"The reactions that break down large molecules into small ones do not require an input of energy, but the reactions that build up large molecules require and input of energy. This is consistent with the laws of thermodynamics, which say that large, orderly molecules tend to break down into small, disorderly molecules." (Stanley A Rice, "Life of Earth: Portrait of a Beautiful, Middle-aged Stressed-out World", 2011)

"The Second Law of Thermodynamics states that in an isolated system (one that is not taking in energy), entropy never decreases. (The First Law is that energy is conserved; the Third, that a temperature of absolute zero is unreachable.) Closed systems inexorably become less structured, less organized, less able to accomplish interesting and useful outcomes, until they slide into an equilibrium of gray, tepid, homogeneous monotony and stay there." (Steven Pinker, "The Second Law of Thermodynamics", 2017)